In order to remove a makeup stain use a non-oily makeup remover.
If the stain persists, dab with a cloth soaked in petrol or ammonia.
Talcum powder, chalk or diatomaceous earth (or diatomite), if necessary, will absorb any residue.
You can also scrub with barely moist natural soap to form a sort of crust.
Let stand for an hour and then lather and rinse.
For specific information, you can also have a look at how to remove a lipstick stain.